Why sky get orange in the evening ?

sky gets its blue color from Rayleigh scattering. Most of the violet light is scattered across the sky, but our eyes aren’t sensitive to violet, so we see the next most scattered color – blue.
In the below image you can see the different layer of colors sun light contains:

Why we see the the orange sky in the evening?

The main cause of the orange, Yellow sky at evening is the color formation of sunlight which we can see in the scattered format in the above picture and the noon the sunlight have to travel shorten distance as compare to evening and due to this in evening the light come at wavelength of 500-600nm which create the color of violet to orange and our eyes are not eligible much to see the violet and green at the sky as the result we see the orange the very next color of sunlight in the scattered format.

To Read in Hindi : शाम को आसमान में नारंगी रंग क्यों आता है?

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